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Page 25
The cost of producing oxygen at Westminster, under specially expensive
conditions, is high--about 12s. per 1,000 cub. ft. When we consider,
however, that the cost should only embrace attendance, fuel, wear and
tear, and a little lime and soda for the purifiers, that the
consumption of fuel is small, the wear and tear light, and that the
raw material--air--is obtained for nothing, it ought to be possible to
produce the gas for a third or fourth of this amount in most of our
great manufacturing centers, where the price of fuel is but a third of
that demanded in London, and where provision could be made for
economizing the waste heat, which is entirely lost in the Westminster
installation. Moreover, in estimating this cost all the charges are
thrown on the oxygen; were there any means of utilizing the 4,000 cub.
ft. of nitrogen at present blown away as waste for every thousand
cubic feet of oxygen produced, the nitrogen would of course bear its
share of the cost.
The question of the application of the oxygen is one which must be
determined in its manifold bearings mainly by the experiments of
chemists and scientific men engaged in industrial work. Having
ascertained the method by which and the limit of cost within which it
is possible to use oxygen in their work, it can be seen whether by
Brin's process the gas can be obtained within that limit.
Mr. S.R. Ogden, the manager of the corporation gasworks at Blackburn,
has already made interesting experiments on the application of oxygen
in the manufacture of illuminating gas. In order to purify coal gas
from compounds of sulphur, it is passed through purifiers charged with
layers of oxide of iron. When the oxide of iron has absorbed as much
sulphur as it can combine with, it is described as "foul." It is then
discharged and spread out in the open air, when, under the influence
of the atmospheric oxygen, it is rapidly decomposed, the sulphur is
separated out in the free state, and oxide of iron is reformed ready
for use again in the purifiers. This process is called revivification,
and it is repeated until the accumulation of sulphur in the oxide is
so great (45 to 55 per cent.) that it can be profitably sold to the
vitriol maker. Hawkins discovered that by introducing about 3 per
cent. of air into the gas before passing it through the purifiers, the
oxygen of the air introduced set free the sulphur from the iron as
fast as it was absorbed. Thus the process of revivification could be
carried on in the purifiers themselves simultaneously with the
absorption of the sulphur impurities in the gas.
A great saving of labor was thus effected, and also an economy in the
use of the iron oxide, which in this way could be left in the
purifiers until charged with 75 per cent. of sulphur. Unfortunately it
was found that this introduction of air for the sake of its oxygen
meant also the introduction of much useless nitrogen, which materially
reduced the illuminating power of the gas. To restore this
illuminating power the gas had to be recarbureted, and this again
meant cost in labor and material. Now, Mr. Ogden has found by a series
of conclusive experiments made during a period of seventy-eight days
upon a quantity of about 4,000,000 cub. ft. of gas, that by
introducing 1 per cent. of oxygen into the gas instead of 3 per cent.
of air, not only is the revivification _in situ_ effected more
satisfactorily than with air, but at the same time the illuminating
power of the gas, so far from being decreased, is actually increased
by one candle unit.
[Illustration: THE PRODUCTION OF OXYGEN BY BRIN'S PROCESS.]
So satisfied is he with his results that he has recommended the
corporation to erect a plant for the production of oxygen at the
Blackburn gas works, by which he estimates that the saving to the town
on the year's make of gas will be something like �2,500. The practical
observations of Mr. Ogden are being followed up by a series of
exhaustive experiments by Mr. Valon, A.M. Inst. C.E., also a gas
engineer. The make of an entire works at Westgate is being treated by
him with oxygen. Mr. Valon has not yet published his report, as the
experiments are not quite complete; but we understand that his results
are even more satisfactory than those obtained at Blackburn.
In conclusion we may indicate a few other of the numerous possible
applications of cheap oxygen which might be realized in the near
future. The greatest illuminating effect from a given bulk of gas is
obtained by mixing it with the requisite proportion of oxygen, and
holding in the flame of the burning mixture a piece of some solid
infusible and non-volatile substance, such as lime. This becomes
heated to whiteness, and emits an intense light know as the Drummond
light, used already for special purposes of illumination. By supplying
oxygen in pipes laid by the side of the ordinary gas mains, it would
be possible to fix small Drummond lights in place of the gas burners
now used in houses; this would greatly reduce the consumption of gas
and increase the light obtained, or even render possible the
employment of cheap non-illuminating combustible gases other than coal
gas for the purpose.
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